The six th viria l coe cient of hard disc mix tures RICHARD

نویسنده

  • RICHARD J. WHEATLEY
چکیده

New calculations of the sixth virial coe cient are presented for binary hard disc mixtures. For each diameter ratio considered, the calculations involve about 1600 9-dimensional integrals. The integrals are evaluated exactly in d dimensions, and approximately, using the Korobov± Conroy number theoretical method, in the other (9­ d ) dimensions, where d is between 4 and 8 for each diagram. The results cover diameter ratios from 0.1 to 0.9, and are accurate to about 0.2% . A method for predicting the sixth virial coe cients for the binary mixture, based on interpolating the sixth virial coe cients for the pure components, gives results within 1% of the calculated values.

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تاریخ انتشار 2004